FMOC-GLYCINE HYDROXYSUCCINIMIDE ESTER;
FMOC-GLYCINE N-HYDROXYSUCCINIMIDE ESTER;
FMOC-GLYCINE-OSU;
N-alpha-(9-Fluorenylmethyloxycarbonyl)-glycine succinimidyl ester;
FMOC-GLYCINE HYDROXYSUCCINIMIDESTER;
N-[(9H-Fluoren-9-ylmethoxy)carbonyl]glycine 2,5-dioxo-1-pyrrolidinyl ester;
(2,5-dioxopyrrolidin-1-yl) 2-(9H-fluoren-9-ylmethoxycarbonylamino)acetate
They are usually used to pack powder. And they can prevent sunshine and water from getting bad.
The hard carton can protect your products from crashing and getting wet.
For Fmoc-GlyGly-OH 1a, Glycine (75 mg, 1 mmol) and NaHCO3 (100 mg, 1.2 mmol) were dissolved in H2O (10 ml) and dimethoxyethane (DME) (5 ml). Fmoc-Gly-NHS solution in DME (5 ml, 1 mmol) was added. THF (2.5 ml) was added, the mixture was sonicated to make it homogeneous and stirred for 20 h. All volatiles were removed on a rotovap, the residue was treated with EtOAc and 5percent KHCO3 solution in H2O. Product was extracted four times with EtOAc, washed with brine at pH=3, dried (Na2SO4), concentrated and dried in vacuo. Yield 321 mg (90percent). MS: 775.0 [2M +2Na]+; 377.4 [M+Na]+; 355.1 [M+1]+.
For Fmoc-Gly-NHS, Fmoc-Gly-OH (891 mg, 3 mmol) and NHS (380 mg, 3.3 mmol) were stirred in THF (10 ml) at 0C for 5 mm and treated with a DCC solution (650 mg, 3.15 mmol) in THF (5 ml). The cooling bath was removed in 30 mm and the reactionmixture was stirred at 20C for 10 h. The solid DCU was filtered off, washed with THF and the solvent was removed on the rotovap. The product was weighed and dissolved in DME to make a 0.2 mlvi solution.
Appearance ： White to off- white powder
3 - Hazards Identification
Do Not Have Hazard For People And Animals
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air.
AFTER SKIN CONTACT In case of contact,
immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact, immediately flush eyes with copious amounts of
water for at least 15 minutes.
5 - Fire Fighting Measures
EXTINGUISHING MEASURES
Suitable : Water spray . Carbon dioxide, dry chemical powder, or
Appropriate foam though it’s hard to burn the material .
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self- contained breathing apparatus and protective
clothing to prevent contact with skin and eyes .
6 - Accidental Release Measures
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal . Avoid raising
dust . Ventilate area and wash spill site after material
pickup is complete .
7 - Handling and Storage
HANDLING
Directions for Safe Handling : Avoid breathing dust . Avoid
contact with eyes .
STORAGE
Conditions of Storage: Use plastic bags and paper drums. Keep
container sealed in room temperature. Away from light.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath . Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling .
PERSONAL PROTECTIVE EQUIPMENT
Eye Protection : Chemical safety goggles.
9 - Physical and Chemical Properties
pH N/A
BP/BP Range N/A
Flash Point ： N/A
Flammability ： N/A
Autoignition Temp N/A
Oxidizing Properties N/ A
Explosive Properties
N/ A Explosion Limits
N/A Vapor Pressure N/A
SG/Density N/A
Partition Coefficient N/ A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc . N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp . N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
ALDRICH - H15403 www.sigma-aldrich.com Page 2
STABILITY Materials to Avoid :
Strong oxidizing agents .
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products : Carbon monoxide, Carbon
dioxide, Nitrogen oxides, Hydrogen chloride gas .
11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation by long term contacting .
Eye Contact: May cause eye irritation .
Multiple Routes : May be harmful by inhalation, ingestion.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Dissolve or mix the material with a combustible solvent and burn in
a chemical incinerator equipped with an afterburner and scrubber .
Observe all federal, state, and local environmental
regulations.
14 - Transport Information
RID/ ADR
Non- hazardous for road transport.
IMDG
Non- hazardous for sea transport.
IATA
Non- hazardous for air transport.
15 Regulatory information
Regulations on the Control over Safety of Dangerous Chemicals
(State Council announces on January 26, 2002 and revised on
February 16,2011) : Safe use and production, the storage of a
dangerous chemical, transport, loading and unloading were
prescribed .
16 - Other Information
Information on revision
Creation Date
Revision Date
Feb 12, 2022
Feb 12, 2025
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide.
The information in this document is based on the present state
of our knowledge and is applicable to the product with regard
to appropriate safety precautions. It does not represent any
guarantee of the properties of the product.
| DL-Gly-OH | N-Benzylglycine | Fmoc-Gly-Gly-OH | DL-leu-Gly |
| Gly-NCA | Pro-Gly-OH | Fmoc-Gly-Gly-Gly-OH | D-Leu-Gly-OH |
| Boc-Gly-Pro-OH | Tos-Gly | Fmoc-Gly-Gly-Gly-Gly-OH | Boc-Leu-Gly-OH |
| Boc-Gly-His(Trt) | Gly-L-Tyr-OH | Fmoc-Gly-Osu | Boc-DL-Leu-Gly-OH |
| Boc-Gly-Tyr-OH | Gly-Sar-OH | Fmoc-N-Me-Gly-OH | Boc-D-Leu-Gly-OH |
| Boc-Gly-Tyr-OMe | Gly-Gly-OH | Fmoc-Gly-glu(otbu)-oh | Fmoc-Leu-Gly |
| Boc-Gly-Gly-OSu | gly-val | Cbz-Gly-Gly-OSU | Boc-Pro-Gly-OH |
| Boc-Gly-Gly-Leu | gly-met | Cbz-Gly-NH2 | Boc-Phe-Gly-Ome |
| Boc-Gly-Gly-Gly | Gly-Ile | Z-Gly-Osu | L-Phe-Gly |
| Boc-Gly-Leu-OH | Gly-Phe | Z-gly-gly-leu-oh | Boc-Phe-Gly |
| Boc-Gly-Obzl | Gly-D-leu | Cbz-Gly-OH | Fmoc-Phe-Gly-OH |
| Boc-Gly-OH | Tos-Gly-Pro-OH | Cbz-Gly-ol | Cbz-Phe-Gly-OH |
| Boc-Gly-Gly-OH | Gly-Gly-Leu | Cbz-Gly-Ome | Cbz-Phe-Gly-Oet |
| Boc-Gly-OSu | Gly-Gly-Gly | Cbz-Gly-Oet | Boc-Phe-Gly-Gly-OH |
| Boc-Gly-NH2 | Ala-gly | Cbz-Gly-Gly-OH | Trp-Gly |
| Boc-Gly-Ile | Ala-Gly-Ome.hcl | Pht-Gly-OtBu | Boc-Trp-Gly |
| Boc-Gly-OtBU | Boc-Ala-Gly-OH | Pht-Gly-Ome-OH | Fmoc-L-Thr(tBu)-Gly-OH |
| Boc-Gly-OMe | Fmoc-Ala-gly-OH | Pht-Gly-OH | Met-Gly.HCl |
| Boc-Gly(OMe)-OH | Fmoc-Ala-gly-OH | AC-Gly-OH | H-Met-Gly-OH |
| Boc-Gly-Oet | val-gly | Ac-Gly-OSU | Cbz-D-Arg-Gly-OH |
| Boc-Gly-Oipr | Boc-Val-Gly-OH | Gly-Ala-Ome.hcl | Boc-His(Trt)-Gly-OH |
| Fmoc-Gly-Ol | Cbz-Val-Gly-OH | Gly-Gly-Ala-Ome.hcl | Boc-Gly-OL |
| Fmoc-Gly-OH | Z-Val-Gly-OET | H-Gly-Gly-Oet .HCL | H-Gly-Ome.HCl |
| Fmoc-Gly-Val-OH | Leu-Gly | H-Gly-Oipr. HCL | Gly-Gly-Ome.HCl |
| Tos-Gly-Ome | Ac-Gly-Oet | H-Gly-Obzl.Tos | Gly-Otbu.Hcl |
| H-Gly-Oet.HCl | Gly-Otbu | Gly-Obzl | For-Gly-OMe |
| Gly.HCL | AC-Gly-Ome | Gly-Obzl.hcl | N-Bzl-Gly-Oet |
| H-Gly-NH2.HCl | Glycine n-octyl ester hydrochloride |
1. R&D service available
2. ISO certified manufacturer, quality guarantee
3.A full course of follow-up service during production
4.High cost effective
5.Quality certification documents provided per customer's request
6.Great after-sales service, maintaining close relationship with customer
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8.Free sample offered to check out quality prior to any payment
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